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Innovative Fluorinated Polyimides with Superior Thermal, Mechanical, and Dielectric Properties for Advanced Soft Electronics
Chen YW(陈钰玮)1; Liu YD(刘屹东)2,3; Min, Yonggang1
Corresponding AuthorLiu, Yidong([email protected]) ; Min, Yonggang([email protected])
Source PublicationPOLYMERS
2025-02-01
Volume17Issue:3Pages:12
AbstractThis study addresses the limitations of traditional polyimides (PIs) in high-frequency and high-temperature soft electronic applications, and then introducing trifluoromethylbenzene (TFMB) into the molecular structure and employing various diamines as connecting components to solve the bottleneck. The innovative molecular design enhances thermal, mechanical, and dielectric properties, overcoming challenges in balancing these performances. The optimized fluorinated PI (TPPI50) exhibits exceptional properties, including a glass transition temperature of 402 degrees C, thermal decomposition temperature of 563 degrees C, tensile strength of 232.73 MPa, elongation at break of 26.26%, and dielectric constant of 2.312 at 1 MHz with a dielectric loss as low as 0.00676. These improvements are attributed to the unique synergy between TFMB's fluorinated groups, which reduce molecular polarization, and the biphenyl structure, which reinforces chain stability. Compared to conventional PIs, TPPI50 demonstrates superior comprehensive performance, making it highly suitable for soft circuits, high-frequency signal transmission, and advanced applications such as wearable devices and biosensors. This study provides a robust framework for industrial applications, offering a path to next-generation soft electronics with enhanced reliability and performance.
Keywordfluorinated polyimide low dielectric constant molecular dynamics DFT
DOI10.3390/polym17030339
Indexed BySCI ; EI
Language英语
WOS IDWOS:001418395600001
WOS KeywordGAUSSIAN-BASIS SETS ; MOLECULAR CALCULATIONS ; ATOMS ; FILMS ; TRANSPARENT
WOS Research AreaPolymer Science
WOS SubjectPolymer Science
Funding ProjectHigh-level Innovation Research Institute Program of Guangdong Province ; National Natural Science Foundation of China[U20A20340] ; Foshan Introducing Innovative and Entrepreneurial Teams[1920001000108] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB0910303] ; [2020B0909010003/GARA2023001000]
Funding OrganizationHigh-level Innovation Research Institute Program of Guangdong Province ; National Natural Science Foundation of China ; Foshan Introducing Innovative and Entrepreneurial Teams ; Strategic Priority Research Program of the Chinese Academy of Sciences
Classification二类/Q1
Ranking1
Contributor刘屹东 ; Min, Yonggang
Citation statistics
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/100078
Collection宽域飞行工程科学与应用中心
Affiliation1.Guangdong Univ Technol, Sch Electromech Engn, Guangzhou HEMC, 100 Waihuanxi Rd, Guangzhou 510006, Peoples R China;
2.Chinese Acad Sci, Inst Mech, Widerange Flight Engn Sci & Applicat Ctr, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China;
3.Guangdong Aerosp Res Acad, Guangzhou 511458, Peoples R China
Recommended Citation
GB/T 7714
Chen YW,Liu YD,Min, Yonggang. Innovative Fluorinated Polyimides with Superior Thermal, Mechanical, and Dielectric Properties for Advanced Soft Electronics[J]. POLYMERS,2025,17,3,:12.Rp_Au:刘屹东, Min, Yonggang
APA 陈钰玮,刘屹东,&Min, Yonggang.(2025).Innovative Fluorinated Polyimides with Superior Thermal, Mechanical, and Dielectric Properties for Advanced Soft Electronics.POLYMERS,17(3),12.
MLA 陈钰玮,et al."Innovative Fluorinated Polyimides with Superior Thermal, Mechanical, and Dielectric Properties for Advanced Soft Electronics".POLYMERS 17.3(2025):12.
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