| Influence of HCl on CO and NO emissions in combustion |
| Wei XL(魏小林) ; Wang Y(王阳); Liu DF(刘典福); Sheng HZ(盛宏至); Wei XL
|
| Source Publication | Fuel
(IF:5.128[JCR-2018],5.223[5-Year]) |
| 2009
|
| Volume | 88Issue:10Pages:1998-2003 |
| ISSN | 0016-2361
|
| Abstract | The influence of HCl on CO and NO emissions was experimentally investigated in an entrained flow reactor (EFR) and an internally circulating fluidized bed (ICFB). The results in EFR show the addition of HCl inhibits CO oxidation and NO formation at 1073 K and 1123 K. At the lower temperature (1073 K) the inhibition of HCl becomes more obvious. In ICFB, chlorine-containing plastic (PVC) was added to increase the concentration of HCl during the combustion of coal or coke. Results show that HCl is likely to enhance the reduction of NO and N2O. HCl greatly increases CO and CH4 emission in the flue gas. A detailed mechanism of CO/NO/HCl/SO2 system was used to model the effect of HCl in combustion. The results indicate that HCl not only promotes the recombination of radicals O, H, and OH, but also accelerates the chemical equilibration of radicals. The influence of HCl on the radicals mainly occurs at 800-1200 K. (C) 2009 Elsevier Ltd. All rights reserved. |
| Keyword | Hcl
Co
No
Efr
Fbc
Circulating Fluidized-bed
Chlorine
Flames
Oxidation
So2
Mechanism
Particle
Kinetics
Sulfur
Scale
|
| DOI | 10.1016/j.fuel.2009.03.009
|
| Indexed By | SCI
|
| Language | 英语
|
| WOS ID | WOS:000268164800027
|
| WOS Keyword | CIRCULATING FLUIDIZED-BED
; CHLORINE
; FLAMES
; OXIDATION
; SO2
; MECHANISM
; PARTICLE
; KINETICS
; SULFUR
; SCALE
|
| WOS Research Area | Energy & Fuels
; Engineering
|
| WOS Subject | Energy & Fuels
; Engineering, Chemical
|
| Funding Organization | National Natural Science Foundation of China [50776099, 50376068]
; Alexander von Humboldt Foundation
|
| Citation statistics |
|
| Document Type | 期刊论文
|
| Identifier | http://dspace.imech.ac.cn/handle/311007/33495
|
| Collection | 等离子体与燃烧中心(2009-2011)
|
| Corresponding Author | Wei XL |
Recommended Citation
GB/T 7714 |
Wei XL,Wang Y,Liu DF,et al. Influence of HCl on CO and NO emissions in combustion[J]. Fuel,2009,88,10,:1998-2003.
|
| APA |
魏小林,王阳,刘典福,盛宏至,&Wei XL.(2009).Influence of HCl on CO and NO emissions in combustion.Fuel,88(10),1998-2003.
|
| MLA |
魏小林,et al."Influence of HCl on CO and NO emissions in combustion".Fuel 88.10(2009):1998-2003.
|
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