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Influence of HCl on CO and NO emissions in combustion
Wei XL(魏小林); Wang Y(王阳); Liu DF(刘典福); Sheng HZ(盛宏至); Wei XL
Source PublicationFuel
2009
Volume88Issue:10Pages:1998-2003
ISSN0016-2361
AbstractThe influence of HCl on CO and NO emissions was experimentally investigated in an entrained flow reactor (EFR) and an internally circulating fluidized bed (ICFB). The results in EFR show the addition of HCl inhibits CO oxidation and NO formation at 1073 K and 1123 K. At the lower temperature (1073 K) the inhibition of HCl becomes more obvious. In ICFB, chlorine-containing plastic (PVC) was added to increase the concentration of HCl during the combustion of coal or coke. Results show that HCl is likely to enhance the reduction of NO and N2O. HCl greatly increases CO and CH4 emission in the flue gas. A detailed mechanism of CO/NO/HCl/SO2 system was used to model the effect of HCl in combustion. The results indicate that HCl not only promotes the recombination of radicals O, H, and OH, but also accelerates the chemical equilibration of radicals. The influence of HCl on the radicals mainly occurs at 800-1200 K. (C) 2009 Elsevier Ltd. All rights reserved.
KeywordHcl Co No Efr Fbc Circulating Fluidized-bed Chlorine Flames Oxidation So2 Mechanism Particle Kinetics Sulfur Scale
DOI10.1016/j.fuel.2009.03.009
Indexed BySCI
Language英语
WOS IDWOS:000268164800027
WOS KeywordCIRCULATING FLUIDIZED-BED ; CHLORINE ; FLAMES ; OXIDATION ; SO2 ; MECHANISM ; PARTICLE ; KINETICS ; SULFUR ; SCALE
WOS Research AreaEnergy & Fuels ; Engineering
WOS SubjectEnergy & Fuels ; Engineering, Chemical
Funding OrganizationNational Natural Science Foundation of China [50776099, 50376068] ; Alexander von Humboldt Foundation
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/33495
Collection等离子体与燃烧中心(2009-2011)
Corresponding AuthorWei XL
Recommended Citation
GB/T 7714
Wei XL,Wang Y,Liu DF,et al. Influence of HCl on CO and NO emissions in combustion[J]. Fuel,2009,88,10,:1998-2003.
APA 魏小林,王阳,刘典福,盛宏至,&Wei XL.(2009).Influence of HCl on CO and NO emissions in combustion.Fuel,88(10),1998-2003.
MLA 魏小林,et al."Influence of HCl on CO and NO emissions in combustion".Fuel 88.10(2009):1998-2003.
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