| Effect of H2O Vapor on NO reduction by CO: experimental and kinetic modeling study | |
Li S(李森) ; Wei XL(魏小林); Guo XF(郭啸峰); Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.
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| Source Publication | ENERGY & FUELS
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| 2012-07-01 | |
| Volume | 26Issue:7Pages:4277-4283 |
| ISSN | 0887-0624 |
| Abstract | The experiment and kinetic modeling prediction were conducted to investigate the effect of H2O vapor on NO reduction by CO. The experiment was performed in a 36-kW combustion reactor, and modeling prediction was done using the plug-flow reactor model. In the presence of H2O, the formation of free-radical H is conducive to NO reduction. H2O has a complex effect on NO emission: at T < 1100 degrees C, NO emission decreases with the increase of H2O content and temperature, the reaction pathway of NO reduction is NO -> HNO -> NH -> N2O -> N-2, and the controlling factors of NO reduction are temperature and H2O concentration;at 1100 degrees C < T < 1400 degrees C, NO emission decreases as the H2O content increases and remains constant with the change of temperature at [H2O] < 1.0%, NO reduction depends on H2O concentration rather than temperature, and increasing H2O concentration makes free-radical H reach high equilibrium concentration; at T > 1400 degrees C, the effects of H2O content and temperature on NO emission at [H2O] < 1.0% are similar to that at T < 1100 degrees C, NO emission increases with H2O content but decreases with temperature at [H2O] >1%, NO reduction depends on the combined effects of H and CO. |
| Keyword | Nitric-oxide Catalytic-reduction Carbon-monoxide Flames |
| Subject Area | 化工流体力学 |
| URL | 查看原文 |
| Indexed By | SCI ; EI |
| Language | 英语 |
| WOS ID | WOS:000306503100034 |
| Funding Organization | Financial support by National Natural Science Foundation of China (No. 50976123) and the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KGCX2-YW-321) is acknowledged. |
| Department | LHD高效洁净燃烧(CPCR) |
| Classification | 二类/Q1 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/46384 |
| Collection | 高温气体动力学国家重点实验室 |
| Corresponding Author | Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China. |
| Recommended Citation GB/T 7714 | Li S,Wei XL,Guo XF,et al. Effect of H2O Vapor on NO reduction by CO: experimental and kinetic modeling study[J]. ENERGY & FUELS,2012,26,7,:4277-4283. |
| APA | Li S,Wei XL,Guo XF,&Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China..(2012).Effect of H2O Vapor on NO reduction by CO: experimental and kinetic modeling study.ENERGY & FUELS,26(7),4277-4283. |
| MLA | Li S,et al."Effect of H2O Vapor on NO reduction by CO: experimental and kinetic modeling study".ENERGY & FUELS 26.7(2012):4277-4283. |
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