Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball | |
Li S(李森); Yu JL; Wei XL(魏小林); Guo XF; Chen Y; Li, S (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China. | |
Source Publication | Fuel Processing Technology |
2014-09 | |
Volume | 125Pages:163-169 |
ISSN | 0378-3820 |
Abstract | The catalytic effect of coal gangue hollow ball with open pores on NO reduction by CO in fluidized bed was investigated, and the kinetics for the catalytic reduction of NO using CO was evaluated. In the absence of water vapor at 773-923 K, the reaction rate constant was k = 5210 exp(-113600/(RT)). NO reduction ratio rapidly increased with reaction residence time at initial stage (<1 s) and T > 873 K; high NO reduction ratio was achieved by increasing reaction temperature when the initial concentration ratio of CO to NO was less than 4. In the presence of water, the catalytic effect of coal gangue hollow ball on NO reduction was weakened, and the reaction rate constant was k = 0.31 exp(-60750/(RT)). NO reduction ratio is less than 02 when reaction residence time was 2.5 s at T <= 923 K when the initial concentration ratio of CO to NO was 4, and the initial concentration ratio of CO to NO had negligible effect on NO reduction ratio at T <= 923 K. (C) 2014 Elsevier B.V. All rights reserved. |
Keyword | Coal Gangue Hollow Ball No Reduction Kinetic Modeling Carbon Monoxide |
Subject Area | Chemistry ; Energy & Fuels ; Engineering |
URL | 查看原文 |
Indexed By | SCI ; EI |
Language | 英语 |
WOS ID | WOS:000337876300020 |
Funding Organization | Financial support by National Natural Science Foundation of China (No. 51376189) is acknowledged. |
Department | LHD高效洁净燃烧(CPCR) |
Classification | 二类 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://dspace.imech.ac.cn/handle/311007/49040 |
Collection | 高温气体动力学国家重点实验室 |
Corresponding Author | Li, S (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China. |
Recommended Citation GB/T 7714 | Li S,Yu JL,Wei XL,et al. Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball[J]. Fuel Processing Technology,2014,125:163-169. |
APA | Li S,Yu JL,Wei XL,Guo XF,Chen Y,&Li, S .(2014).Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball.Fuel Processing Technology,125,163-169. |
MLA | Li S,et al."Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball".Fuel Processing Technology 125(2014):163-169. |
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