Geometric design of micron-sized crystalline silicon anodes through in situ observation of deformation and fracture behaviors | |
Zhang Xing-yu; Song WL; Liu ZL; Chen HS; Li T; Wei YJ(魏宇杰); Fang DN; Fang, DN (reprint author), Peking Univ, Coll Engn, State Key Lab Turbulence & Complex Syst, Beijing 100871, Peoples R China. | |
Source Publication | JOURNAL OF MATERIALS CHEMISTRY A |
2017-07-07 | |
Volume | 5Issue:25Pages:12793-12802 |
ISSN | 2050-7488 |
Abstract | Large anisotropic volume expansion during lithiation leads to the electrochemical performance degradation and premature fracture of micro-sized silicon electrodes in lithium-ion batteries, which prohibits its practical applications. To date, the failure mechanism of micron-size silicon electrodes has not been fully comprehended due to the lack of convincing experiments. For good understanding of lithiation/delithiation processes in the silicon anodes, in the present contribution, in situ observation of anisotropic volume expansion, crack initiation, penetration, deflection and delamination at the amorphous/crystalline silicon interface has been reported. The observation suggests that novel hollow and anisometric geometric electrodes have shown substantially enhanced capability in improving the fracture behaviors of the crystalline micropillar electrodes, implying that geometric design greatly impacts the strain alleviation and reversible volume change. Due to more favorable mechanical reliability, the anisometric geometric silicon electrode is expected to present essentially enhanced electrochemical performance and structural stability, which promises a novel strategy of designing Li-ion battery electrodes from a geometric perspective. |
DOI | 10.1039/c7ta02527k |
Indexed By | SCI ; EI |
Language | 英语 |
WOS ID | WOS:000404571500018 |
WOS Keyword | LITHIUM-ION BATTERIES ; NEGATIVE ELECTRODES ; ENERGY DENSITY ; LITHIATION ; LI ; INSERTION ; NANOPILLARS ; PARTICLES ; KINETICS ; FAILURE |
WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
WOS Subject | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
Funding Organization | National Natural Science Foundation of China(11672341||Foundation for Innovative Research Groups of the National Natural Science Foundation of China(11521202)||National Materials Genome Project(2016YFB0700600)||111572002) |
Department | LNM微结构计算力学 |
Classification | 一类 |
Ranking | 1 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://dspace.imech.ac.cn/handle/311007/60634 |
Collection | 非线性力学国家重点实验室 |
Corresponding Author | Fang, DN (reprint author), Peking Univ, Coll Engn, State Key Lab Turbulence & Complex Syst, Beijing 100871, Peoples R China. |
Recommended Citation GB/T 7714 | Zhang Xing-yu,Song WL,Liu ZL,et al. Geometric design of micron-sized crystalline silicon anodes through in situ observation of deformation and fracture behaviors[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5,25,:12793-12802. |
APA | Zhang Xing-yu.,Song WL.,Liu ZL.,Chen HS.,Li T.,...&Fang, DN .(2017).Geometric design of micron-sized crystalline silicon anodes through in situ observation of deformation and fracture behaviors.JOURNAL OF MATERIALS CHEMISTRY A,5(25),12793-12802. |
MLA | Zhang Xing-yu,et al."Geometric design of micron-sized crystalline silicon anodes through in situ observation of deformation and fracture behaviors".JOURNAL OF MATERIALS CHEMISTRY A 5.25(2017):12793-12802. |
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