| Self-sustained CO Combustion Induced by CuCe0.75Zr0.25Oy Catalysts with Different Pore-forming Methods | |
He JY1,2; Kang RN(康润宁)1,3 ; Zhang Q4; Wei XL(魏小林)1,3; Dou BJ4; Bin F(宾峰)1
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| Corresponding Author | Wei, Xiaolin([email protected]) ; Dou, Baojuan([email protected]) |
| Source Publication | COMBUSTION SCIENCE AND TECHNOLOGY
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| 2020-02-16 | |
| Pages | 13 |
| ISSN | 0010-2202 |
| Abstract | CO self-sustaining combustion, induced by a CuCe0.75Zr0.25Oy catalyst, has been confirmed experimentally as an effective strategy to reduce serious environmental pollution and energy waste, which is caused by direct combustion of conventional converter gas in the steelmaking industry. In this paper, the effects of CuCe0.75Zr0.25Oy catalysts prepared by a sol-gel method via three different pore-forming agents (oxalic acid, cellulose and thermal decomposition) were investigated for their catalytic activity of self-sustained CO combustion. Additionally, characterization methods were used to obtain the structural properties of each catalyst. The results obtained show that the CuCe0.75Zr0.25Oy catalyst, as a sol-gel pore-forming agent, prepared from cellulose exhibits the highest activity among the three catalysts. Under the condition of a reaction gas (3% CO+5% O-2/N-2), the T-10 (70 degrees C), T-50 (73 degrees C) and T-90 (78 degrees C) of the cellulose catalyst are obviously lower than those of the other catalysts, where T-10, T-50 and T-90 denote the reaction temperature corresponding to the CO conversion of 10%, 50% and 90%, respectively. The reason is that the cellulose pore-forming agent promotes the formation of a multistage porous structure, which strengthens the synergistic effect between the Cu and Ce catalysts and changes the redox property of the overall catalyst. On the one hand, the strong synergy between CuO and CeO2 adjusts the dispersion and chemical state of copper nanoparticles. On the other hand, the oxygen vacancies generated locate at the copper-cerium interface enhance the ability of oxygen storage and oxygen release of the catalyst. |
| Keyword | CuCe0 75Zr0 25O(y) catalyst carbon monoxide self-sustained combustion pore-forming way |
| DOI | 10.1080/00102202.2020.1727455 |
| Indexed By | SCI ; EI |
| Language | 英语 |
| WOS ID | WOS:000514554400001 |
| WOS Keyword | VOLATILE ORGANIC-COMPOUNDS ; REACTION-MECHANISM ; OXIDATION ; CU ; REMOVAL ; PERFORMANCE ; TOLUENE ; MN ; CHLOROBENZENE ; ENHANCEMENT |
| WOS Research Area | Thermodynamics ; Energy & Fuels ; Engineering |
| WOS Subject | Thermodynamics ; Energy & Fuels ; Engineering, Multidisciplinary ; Engineering, Chemical |
| Funding Project | National Natural Science Foundation of China[51736010] ; National Natural Science Foundation of China[51776216] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21040500] |
| Funding Organization | National Natural Science Foundation of China ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences |
| Classification | 二类 |
| Ranking | 1 |
| Contributor | Wei, Xiaolin ; Dou, Baojuan |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/81629 |
| Collection | 高温气体动力学国家重点实验室 |
| Affiliation | 1.Chinese Acad Sci, State Key Lab High Temp Gas Dynam, Inst Mech, Beijing 100190, Peoples R China; 2.Xi'an Jiaotong Univ, Sch Energy & Power Engn, Xian, Peoples R China; 3.Univ Chinese Acad Sci, Sch Engn Sci, Beijing, Peoples R China; 4.Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, Tianjin, Peoples R China |
| Recommended Citation GB/T 7714 | He JY,Kang RN,Zhang Q,et al. Self-sustained CO Combustion Induced by CuCe0.75Zr0.25Oy Catalysts with Different Pore-forming Methods[J]. COMBUSTION SCIENCE AND TECHNOLOGY,2020:13.Rp_Au:Wei, Xiaolin, Dou, Baojuan |
| APA | He JY,康润宁,Zhang Q,魏小林,Dou BJ,&宾峰.(2020).Self-sustained CO Combustion Induced by CuCe0.75Zr0.25Oy Catalysts with Different Pore-forming Methods.COMBUSTION SCIENCE AND TECHNOLOGY,13. |
| MLA | He JY,et al."Self-sustained CO Combustion Induced by CuCe0.75Zr0.25Oy Catalysts with Different Pore-forming Methods".COMBUSTION SCIENCE AND TECHNOLOGY (2020):13. |
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| Jp2020014.pdf（2285KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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