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Slagging characteristics caused by alkali and alkaline earth metals during municipal solid waste and sewage sludge co-incineration
Zhao J(赵京)1,2,3,4; Li B(李博)1; Wei XL(魏小林)1,3; Zhang YF(张玉峰)1,3; Li T(李腾)1
Source PublicationENERGY
2020-07-01
Volume202Pages:8
ISSN0360-5442
AbstractMunicipal solid waste (MSW) and sewage sludge co-incineration is developing into a new method for sludge treatment. However, waste and sludge containing high levels of alkali and alkaline earth metals (AAEMs) will likely cause slagging, corrosion and deterioration of materials during incineration. The occurrence of AAEMs is studied through extraction experiments. Additionally, the surface microstructure and composition of samples are analyzed by SEM-EDS. XRF and XRD are used to analyze the content and crystalline phases of AAEMs. The experimental results indicate that slagging samples are characterized by high amounts of Ca, Na, K, Cl, and S elements. The samples contain numerous irregular particles due to the condensation and nucleation of AAEMs. The extraction experiments and XRD analyses indicate that the insoluble AAEMs are primarily Ca-diopside and gehlenite and Na and K-aluminosilicates in the furnace. The ammonium acetate-soluble Ca consists mainly of sulfates, and the water-soluble Na and K consist of alkali chlorides in the superheaters. In the reaction tower, AAEMs mainly exist as carbonates and the slagging mechanisms are caused by soda manufacture process. The transformation and deposition of AAEMs enhance the slagging and reduce the heat transfer efficiency. The release of AAEMs can be effectively decreased through using sludge granulation technology during MSW and sludge co-incineration, and the furnace running time is extended. (C) 2020 Elsevier Ltd. All rights reserved.
KeywordMunicipal solid waste Sludge Co-incineration Alkali and alkaline earth metals Slagging Sludge granulation
DOI10.1016/j.energy.2020.117773
Indexed BySCI ; EI
Language英语
WOS IDWOS:000538592700088
WOS KeywordHEAVY-METALS ; FLY ASHES ; BEHAVIOR ; RELEASE ; BIOMASS ; COMBUSTION ; DEPOSITS ; CHLORIDE ; SODIUM ; TRANSFORMATION
WOS Research AreaThermodynamics ; Energy & Fuels
WOS SubjectThermodynamics ; Energy & Fuels
Funding OrganizationNational Natural Science Foundation of China[51736010]
Classification一类
Ranking1
ContributorLi, Bo
Citation statistics
Cited Times:45[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/84752
Collection高温气体动力学国家重点实验室
Affiliation1.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China;
2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China;
3.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China;
4.Suzhou Hailu Heavy Ind Co Ltd, Zhangjiagang 215600, Peoples R China
Recommended Citation
GB/T 7714
Zhao J,Li B,Wei XL,et al. Slagging characteristics caused by alkali and alkaline earth metals during municipal solid waste and sewage sludge co-incineration[J]. ENERGY,2020,202:8.Rp_Au:Li, Bo
APA 赵京,李博,魏小林,张玉峰,&李腾.(2020).Slagging characteristics caused by alkali and alkaline earth metals during municipal solid waste and sewage sludge co-incineration.ENERGY,202,8.
MLA 赵京,et al."Slagging characteristics caused by alkali and alkaline earth metals during municipal solid waste and sewage sludge co-incineration".ENERGY 202(2020):8.
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