Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode | |
Shen J(沈嘉)1,2; Liu W(刘巍)1; Niu Y(牛宇)1; Li M3; Jin G(靳刚)1 | |
Corresponding Author | Niu, Yu([email protected]) ; Li, Meng([email protected]) |
Source Publication | JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B |
2020-03-01 | |
Volume | 38Issue:2Pages:7 |
ISSN | 2166-2746 |
Abstract | Biochemical oxygen demand (BOD) is an important indicator for characterizing organic pollution in water. So various BOD sensors have been developed for BOD detection. BOD sensors based on a Clark electrode have the problem of signal drift. To overcome this problem, a combined electrochemical and total internal reflection imaging ellipsometry sensor has been proposed. To improve the sensitivity, polyaniline (PAn) and PAn incorporated with Fe(III) meso-tetra (4-sulfonatophenyl) porphyrin (FeTSPP) have been introduced on the working electrode. The results show that the combination system is effective for BOD detection with PAn. By incorporating FeTSPP, the optical and electrochemical responses of a PAn modified gold chip to BOD are improved significantly. Finally, the relationship between the optical and electrochemical signals is investigated by establishing a glass/Au/PAn-based film/liquid model. The analysis reveals that both signals represent the ratio change of the oxidized state of PAn in a similar way. |
DOI | 10.1116/1.5129606 |
Indexed By | SCI ; EI |
Language | 英语 |
WOS ID | WOS:000569100800005 |
WOS Keyword | DISSOLVED-OXYGEN ; BIOSENSOR ; SENSOR ; FILM |
WOS Research Area | Engineering ; Science & Technology - Other Topics ; Physics |
WOS Subject | Engineering, Electrical & Electronic ; Nanoscience & Nanotechnology ; Physics, Applied |
Funding Project | Youth Innovation Promotion Association of the Chinese Academy of Sciences[2017026] ; National Natural Science Foundation of China (NNSFC)[81872584] ; National Basic Research Program of China[2015CB352100] ; International Science and Technology Cooperation Program of China[2015DFG32390] |
Funding Organization | Youth Innovation Promotion Association of the Chinese Academy of Sciences ; National Natural Science Foundation of China (NNSFC) ; National Basic Research Program of China ; International Science and Technology Cooperation Program of China |
Classification | Q3 |
Ranking | 1 |
Contributor | Niu, Yu ; Li, Meng |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://dspace.imech.ac.cn/handle/311007/85223 |
Collection | 微重力重点实验室 |
Affiliation | 1.Chinese Acad Sci, Inst Mech, Beijing Key Lab Engn Construct & Mech, NML, 15 Bei Si Huan West, Beijing 100190, Peoples R China; 2.Univ Chinese Acad Sci, Sch Engn Sci, 19 Yu Quan Rd, Beijing 100049, Peoples R China; 3.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China |
Recommended Citation GB/T 7714 | Shen J,Liu W,Niu Y,et al. Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,2020,38,2,:7.Rp_Au:Niu, Yu, Li, Meng |
APA | 沈嘉,刘巍,牛宇,Li M,&靳刚.(2020).Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode.JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,38(2),7. |
MLA | 沈嘉,et al."Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode".JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B 38.2(2020):7. |
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