IMECH-IR  > 高温气体动力学国家重点实验室
Non-equilibrium plasma enhanced oxygen vacancies of CuO/CeO2 nanorod catalysts for toluene oxidation
Yun, Jianyu1; Wu, Liangkai1; Hao, Qinglan1; Teng, Zihao1; Gao, Xin1; Dou, Baojuan1; Bin F(宾峰)2
Corresponding AuthorDou, Baojuan([email protected]) ; Bin, Feng([email protected])
Source PublicationJOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
2022-06-01
Volume10Issue:3Pages:8
ISSN2213-2929
AbstractThe development of non-noble metal catalyst is essential for VOCs controlling. Cu-Ce based catalyst is a promising catalyst, and the oxygen vacancies dominants the catalytic oxidation process but the traditional calcination is not conducive to its generation. Herein a series of CuO/CeO2 nanorod catalysts for toluene oxidation were prepared with non-equilibrium plasma comparing with traditional calcination. It is found that the treatment of non-equilibrium plasma after calcination can significantly enhance the synergism between CuO active phase and CeO2 support leading to high dispersion of CuO. And the non-equilibrium plasma is favorable to increase Cu+/Cu2+ and Ce3+/Ce4+ ratios generating more oxygen vacancies in the catalyst. In the process of toluene oxidation, the rich oxygen vacancy can accelerate adsorption and activation of gaseous oxygen which consequently improve the catalytic activity for toluene oxidation.
KeywordNon-equilibrium plasma CuO/CeO2 Oxygen vacancy VOCs Catalytic oxidation
DOI10.1016/j.jece.2022.107847
Indexed BySCI
Language英语
WOS IDWOS:000805826600004
WOS KeywordORGANIC-COMPOUNDS VOCS ; CUO-CEO2 CATALYSTS ; CHLORINATED VOCS ; REMOVAL ; OXIDES ; CO ; CU ; MN ; CHLOROBENZENE ; COMBUSTION
WOS Research AreaEngineering
WOS SubjectEngineering, Environmental ; Engineering, Chemical
Funding ProjectTianjin Municipal Natural Science Foundation[19JCZDJC40100] ; Guangxi Key Research and Development Program[2021AB25028]
Funding OrganizationTianjin Municipal Natural Science Foundation ; Guangxi Key Research and Development Program
Classification一类
Ranking1
ContributorDou, Baojuan ; Bin, Feng
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/89604
Collection高温气体动力学国家重点实验室
Affiliation1.Tianjin Univ Sci & Technol, Tianjin 300457, Peoples R China;
2.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yun, Jianyu,Wu, Liangkai,Hao, Qinglan,et al. Non-equilibrium plasma enhanced oxygen vacancies of CuO/CeO2 nanorod catalysts for toluene oxidation[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2022,10,3,:8.Rp_Au:Dou, Baojuan, Bin, Feng
APA Yun, Jianyu.,Wu, Liangkai.,Hao, Qinglan.,Teng, Zihao.,Gao, Xin.,...&宾峰.(2022).Non-equilibrium plasma enhanced oxygen vacancies of CuO/CeO2 nanorod catalysts for toluene oxidation.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,10(3),8.
MLA Yun, Jianyu,et al."Non-equilibrium plasma enhanced oxygen vacancies of CuO/CeO2 nanorod catalysts for toluene oxidation".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 10.3(2022):8.
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