| Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose | |
Ma PD(马盼东); Zhang CH(张陈航); Dou, Baojuan; Yi, Xiaokun; Bin F(宾峰) ; Liang, Wenjun
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| Corresponding Author | Bin, Feng([email protected]) ; Liang, Wenjun([email protected]) |
| Source Publication | CHEMOSPHERE
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| 2023-02-01 | |
| Volume | 314Pages:11 |
| ISSN | 0045-6535 |
| Abstract | Cubic Cu2O micro/nanocrystals were successfully synthesized by liquid-phase reduction using copper salt of CuSO4 or CuCl2.2H2O, and glucose or ascorbic acid as reducing agent, respectively. The activity of the catalysts was evaluated by light-off curves of CO self-sustained catalytic combustion via temperature-programmed oxidation of CO (CO-TPO), with the results showing the activity of catalysts following the order of Cu2O-ClGLU > Cu2O-S-GLU > Cu2O-S-AA > Cu2O-Cl-AA, (Cl denotes CuCl2.2H2O, GLU denotes glucose, S denotes CuSO4 and AA denotes ascorbic acid, respectively), corresponding to the ignition temperature of 109 degrees C, 122 degrees C, 137 degrees C and 186 degrees C, respectively. The crystal structure, elemental valence, morphology and redox property of the prepared catalysts were analyzed by using various characterization techniques. Combined with in situ infrared spectrum, the CO self-sustained catalytic combustion over Cu2O catalysts mainly follows the Mars-van-Krevelen (M-v-K) mechanism: the adsorbed and activated CO reacts with lattice oxygen to yield CO2 and oxygen vacancy, and then the oxygen vacancy can be replenished by gaseous oxygen. Combined with catalytic performance of high-concentration CO, it is found that the catalysts prepared using glucose as reducing agent are more angular compared with ascorbic acid. The Cu2O-Cl-GLU synthesized with glucose and CuCl2.2H2O exhibits the best catalytic activity among all the catalysts tested, attributing to its more obvious edge and rough crystal surface. The unique structure of Cu2O-Cl-GLU leads to the high exposure rate and coordination unsaturation of atoms on the cubic Cu2O micro/nanocrystals that can improve the ability of activating gaseous O2 and low temperature reducibility, and consequently facilitating the catalytic activity. |
| Keyword | Cu 2 O micro Nanocrystals Carbon monoxide Self-sustained catalytic combustion Chemically adsorbed oxygen |
| DOI | 10.1016/j.chemosphere.2022.137720 |
| Indexed By | SCI ; EI |
| Language | 英语 |
| WOS ID | WOS:000917329000001 |
| WOS Keyword | SELF-SUSTAINED COMBUSTION ; CUPROUS-OXIDE ; CARBON-MONOXIDE ; SCALE SYNTHESIS ; CUO ; PERFORMANCE ; OXIDATION ; NANOCUBES ; REDUCTION ; EVOLUTION |
| WOS Research Area | Environmental Sciences & Ecology |
| WOS Subject | Environmental Sciences |
| Funding Project | Novel Technology of High Efficient Clean Combustion and Energy Saving on Converter Gas[XDA21040500] ; National Natural Science Foundation of China[52176141] |
| Funding Organization | Novel Technology of High Efficient Clean Combustion and Energy Saving on Converter Gas ; National Natural Science Foundation of China |
| Classification | 一类 |
| Ranking | 1 |
| Contributor | Bin, Feng ; Liang, Wenjun |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/91582 |
| Collection | 高温气体动力学国家重点实验室 |
| Recommended Citation GB/T 7714 | Ma PD,Zhang CH,Dou, Baojuan,et al. Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose[J]. CHEMOSPHERE,2023,314:11.Rp_Au:Bin, Feng, Liang, Wenjun |
| APA | 马盼东,张陈航,Dou, Baojuan,Yi, Xiaokun,宾峰,&Liang, Wenjun.(2023).Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose.CHEMOSPHERE,314,11. |
| MLA | 马盼东,et al."Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose".CHEMOSPHERE 314(2023):11. |
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| Jp2023Fa050.pdf（5261KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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