| Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries | |
| Wu, Baolin; Chen CG(陈春光); Danilov, Dmitri L; Chen, Zhiqiang; Jiang, Ming; Eichel, Ruedigera; Notten, Peter Hl | |
| Source Publication | ENERGY & ENVIRONMENTAL MATERIALS
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| 2023-06-06 | |
| Abstract | Anode-free Li-metal batteries are of significant interest to energy storage industries due to their intrinsically high energy. However, the accumulative Li dendrites and dead Li continuously consume active Li during cycling. That results in a short lifetime and low Coulombic efficiency of anode-free Li-metal batteries. Introducing effective electrolyte additives can improve the Li deposition homogeneity and solid electrolyte interphase (SEI) stability for anode-free Li-metal batteries. Herein, we reveal that introducing dual additives, composed of LiAsF6 and fluoroethylene carbonate, into a low-cost commercial carbonate electrolyte will boost the cycle life and average Coulombic efficiency of NMC||Cu anode-free Li-metal batteries. The NMC||Cu anode-free Li-metal batteries with the dual additives exhibit a capacity retention of about 75% after 50 cycles, much higher than those with bare electrolytes (35%). The average Coulombic efficiency of the NMC||Cu anode-free Li-metal batteries with additives can maintain 98.3% over 100 cycles. In contrast, the average Coulombic efficiency without additives rapidly decline to 97% after only 50 cycles. In situ Raman measurements reveal that the prepared dual additives facilitate denser and smoother Li morphology during Li deposition. The dual additives significantly suppress the Li dendrite growth, enabling stable SEI formation on anode and cathode surfaces. Our results provide a broad view of developing low-cost and high-effective functional electrolytes for high-energy and long-life anode-free Li-metal batteries. |
| Keyword | anode-free lithium metal battery dual additives in situ Raman Li growth SEI formation |
| DOI | 10.1002/eem2.12642 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:001007634700001 |
| WOS Research Area | Materials Science, Multidisciplinary |
| Funding Organization | China Scholarship Council |
| Classification | 一类 |
| Ranking | 1 |
| Contributor | Danilov, DL ; Notten, PHL (corresponding author), Forschungszentrum Julich IEK 9, D-52425 Julich, Germany. ; Chen, CG (corresponding author), Chinese Acad Sci, LNM Inst Mech, Beijing 100190, Peoples R China. ; Chen, CG (corresponding author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China. ; Danilov, DL ; Notten, PHL (corresponding author), Eindhoven Univ Technol, POB 513, NL-5600 MB Eindhoven, Netherlands. ; Notten, PHL (corresponding author), Univ Technol Sydney, Sydney, NSW 2007, Australia. |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/92379 |
| Collection | 非线性力学国家重点实验室 |
| Affiliation | 1.{Wu Baolin, Danilov Dmitri L., Eichel Ruediger-A., Notten Peter H. L.} Forschungszentrum Julich IEK 9 D-52425 Julich Germany 2.{Wu Baolin, Eichel Ruediger-A.} Rhein Westfal TH Aachen D-52074 Aachen Germany 3.{Chen Chunguang} Chinese Acad Sci LNM Inst Mech Beijing 100190 Peoples R China 4.{Chen Chunguang} Univ Chinese Acad Sci Sch Engn Sci Beijing 100049 Peoples R China 5.{Danilov Dmitri L., Chen Zhiqiang, Notten Peter H. L.} Eindhoven Univ Technol POB 513 NL-5600 MB Eindhoven Netherlands 6.{Jiang Ming} Hangzhou Dianzi Univ Inst Carbon Neutral & New Energy Sch Elect & Informat Hangzhou 310018 Peoples R China 7.{Notten Peter H. L.} Univ Technol Sydney Sydney NSW 2007 Australia |
| Recommended Citation GB/T 7714 | Wu, Baolin,Chen CG,Danilov, Dmitri L,et al. Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries[J]. ENERGY & ENVIRONMENTAL MATERIALS,2023.Rp_Au:Danilov, DL, Notten, PHL (corresponding author), Forschungszentrum Julich IEK 9, D-52425 Julich, Germany., Chen, CG (corresponding author), Chinese Acad Sci, LNM Inst Mech, Beijing 100190, Peoples R China., Chen, CG (corresponding author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China., Danilov, DL, Notten, PHL (corresponding author), Eindhoven Univ Technol, POB 513, NL-5600 MB Eindhoven, Netherlands., Notten, PHL (corresponding author), Univ Technol Sydney, Sydney, NSW 2007, Australia. |
| APA | Wu, Baolin.,陈春光.,Danilov, Dmitri L.,Chen, Zhiqiang.,Jiang, Ming.,...&Notten, Peter Hl.(2023).Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries.ENERGY & ENVIRONMENTAL MATERIALS. |
| MLA | Wu, Baolin,et al."Dual Additives for Stabilizing Li Deposition and SEI Formation in Anode-Free Li-Metal Batteries".ENERGY & ENVIRONMENTAL MATERIALS (2023). |
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| Jp2023Fa013.pdf（2871KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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