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Achieving superlubricity and high adhesion strength of hydrogenated amorphous carbon film with Al/Cr/Si-doping
Ma, Quansheng; Fu, Yongqiang; Xu Y(许亿); Ma, Tianbao
Corresponding AuthorFu, Yongqiang([email protected]) ; Xu, Yi([email protected]) ; Ma, Tianbao([email protected])
Source PublicationCARBON
2023-11-01
Volume215Pages:10
ISSN0008-6223
AbstractExcellent tribological properties of hydrogenated amorphous carbon films make it an important candidate for friction reduction in industry. However, the great challenge of achieving both high adhesion strength and super-low friction limits its wide applications. In this work, a novel Al, Cr and Si co-doped hydrogenated amorphous carbon (AlCrSi/a-C:H) film was prepared by high-power impulse magnetron sputtering (HiPIMS) method. The AlCrSi/a-C:H film showed favorable mechanical performance and high adhesion (similar to 80 N), which was attributed to the controlled elements doping and special transition layers produced by HiPIMS method. Meanwhile, superlubricity was obtained with coefficient of friction 0.0014. Detailed characterizations suggested that doping elements played significant roles in tribo-chemical reactions during friction. On one hand, doping elements can promote shear-induced graphitization and formation of graphite-like layers at the friction interface. On the other hand, the preferential oxidation of doping elements can protect the formed graphite-like layers from oxidation and the formed oxides nanoparticles can also be wrapped by carbon layers to prevent abrasive wear. It was the synergistic effects of graphitization and oxidation actions that led to superlubricity state of the film. The proposed AlCrSi/a-C:H film architecture with strong adhesion and superlubricity properties provides design criteria of superlubricious films for industrial applications.
KeywordAlCrSi/a-C:H Co -doping Superlubricity Adhesion strength
DOI10.1016/j.carbon.2023.118424
Indexed BySCI ; EI
Language英语
WOS IDWOS:001075708200001
WOS KeywordSUPER-LOW FRICTION ; TRIBOLOGICAL PROPERTIES ; MECHANICAL-PROPERTIES ; DLC FILMS ; MICROSTRUCTURE ; AL ; COATINGS ; PERFORMANCE ; GRAPHENE ; CHROMIUM
WOS Research AreaChemistry ; Materials Science
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary
Funding ProjectNational Natural Science Foundation of China[52225502] ; National Natural Science Foundation of China[52301068] ; National Natural Science Foundation of China[52205204] ; National Key R & D Program of China[:2021YFB3500100]
Funding OrganizationNational Natural Science Foundation of China ; National Key R & D Program of China
Classification一类
Ranking1
ContributorFu, Yongqiang ; Xu, Yi ; Ma, Tianbao
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/93129
Collection宽域飞行工程科学与应用中心
Recommended Citation
GB/T 7714
Ma, Quansheng,Fu, Yongqiang,Xu Y,et al. Achieving superlubricity and high adhesion strength of hydrogenated amorphous carbon film with Al/Cr/Si-doping[J]. CARBON,2023,215:10.Rp_Au:Fu, Yongqiang, Xu, Yi, Ma, Tianbao
APA Ma, Quansheng,Fu, Yongqiang,许亿,&Ma, Tianbao.(2023).Achieving superlubricity and high adhesion strength of hydrogenated amorphous carbon film with Al/Cr/Si-doping.CARBON,215,10.
MLA Ma, Quansheng,et al."Achieving superlubricity and high adhesion strength of hydrogenated amorphous carbon film with Al/Cr/Si-doping".CARBON 215(2023):10.
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