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Discontinuous phase diagram of amorphous carbons
Zhu, Yinbo1; Fang, Zhouyu1; Zhang, Zhongting1; Wu HA(吴恒安)1,2
Source PublicationNATIONAL SCIENCE REVIEW
2024-02-13
Volume11Issue:4Pages:8
ISSN2095-5138
Abstract

The short-range order and medium-range order of amorphous carbons demonstrated in experiments allow us to rethink whether there exist intrinsic properties hidden by atomic disordering. Here we presented six representative phases of amorphous carbons (0.1-3.4 g/cm3), namely, disordered graphene network (DGN), high-density amorphous carbon (HDAC), amorphous diaphite (a-DG), amorphous diamond (a-D), paracrystalline diamond (p-D), and nano-polycrystalline diamond (NPD), respectively, classified by their topological features and microstructural characterizations that are comparable with experiments. To achieve a comprehensive physical landscape for amorphous carbons, a phase diagram was plotted in the sp3/sp2 versus density plane, in which the counterintuitive discontinuity originates from the inherent difference in topological microstructures, further guiding us to discover a variety of phase transitions among different amorphous carbons. Intriguingly, the power law, log(sp3/sp2) proportional to rho n, hints at intrinsic topology and hidden order in amorphous carbons, providing an insightful perspective to reacquaint atomic disorder in non-crystalline carbons. A phase diagram for amorphous carbons was plotted in the sp3/sp2 versus density plane, where counterintuitive discontinuity originates from inherent differences in topological microstructures, further guiding us to discover various phase transitions.

Keywordamorphous carbons disordered carbons phase diagram microstructural topology phase transition
DOI10.1093/nsr/nwae051
Indexed BySCI ; EI ; CSCD
Language英语
WOS IDWOS:001209402100008
WOS KeywordDIAMOND
WOS Research AreaScience & Technology - Other Topics
WOS SubjectMultidisciplinary Sciences
Funding ProjectYouth Innovation Promotion Association of the Chinese Academy of Sciences ; Supercomputing Center of University of Science and Technology of China ; Hefei Advanced Computing Center
Funding OrganizationYouth Innovation Promotion Association of the Chinese Academy of Sciences ; Supercomputing Center of University of Science and Technology of China ; Hefei Advanced Computing Center
Classification一类
Ranking1
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/95017
Collection非线性力学国家重点实验室
Corresponding AuthorWu HA(吴恒安)
Affiliation1.Univ Sci & Technol China, Dept Modern Mech, CAS Key Lab Mech Behav & Design Mat, Hefei 230027, Peoples R China
2.Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Yinbo,Fang, Zhouyu,Zhang, Zhongting,et al. Discontinuous phase diagram of amorphous carbons[J]. NATIONAL SCIENCE REVIEW,2024,11,4,:8.
APA Zhu, Yinbo,Fang, Zhouyu,Zhang, Zhongting,&Wu HA.(2024).Discontinuous phase diagram of amorphous carbons.NATIONAL SCIENCE REVIEW,11(4),8.
MLA Zhu, Yinbo,et al."Discontinuous phase diagram of amorphous carbons".NATIONAL SCIENCE REVIEW 11.4(2024):8.
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