| Multiple potential phase-separation paths in multi-principal element alloys | |
Cao PY(曹沛宇)1; Liu F(刘峰)1; Yuan FP(袁福平)1,2 ; Ma, En3; Wu XL(武晓雷)1,2
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| Corresponding Author | Ma, En([email protected]) ; Wu, Xiao-Lei([email protected]) |
| Source Publication | MATERIALS TODAY NANO
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| 2024-12-01 | |
| Volume | 28Pages:10 |
| ISSN | 2588-8420 |
| Abstract | It is now well established that multi-principal element alloys (MPEAs) offer ample opportunities for exploring new compositions beyond those accessed previously by conventional alloys. However, there is one more realm of possibility presented by MPEAs that has not been touch upon thus far. Here we show that, different from conventional alloys based on a single host element, a given starting MPEA solid solution on its way towards equilibrium can take a rich variety of potential decomposition pathways via multi-stage phase separation, offering a wide range of composition destinations. If/when some of them are reached, assuming kinetically allowed, the multiple phase separation reactions one after another would lead to domains that are compositionally complex and spatially localized. This hypothetical scenario is demonstrated in this paper using a model that mimics Cr-CoNi MPEA, showing a preponderance of multiplicity even when assuming only fcc-based phases can form. The complex chemical heterogeneities created as such are expected to be an additional knob to turn for tuning spatially variable composition and chemical order and therefore mechanical properties. Our results thus advocate multiple phase separation possibilities with many potential paths and terminal chemical heterogeneities as yet another important characteristic that distinguishes MPEAs from conventional alloys. |
| Keyword | Multi-principal element alloy Phase separation Nucleation-growth Spinodal decomposition Short-range order Heterogeneity |
| DOI | 10.1016/j.mtnano.2024.100511 |
| Indexed By | SCI ; EI |
| Language | 英语 |
| WOS ID | WOS:001305555500001 |
| WOS Keyword | SHORT-RANGE ORDER ; HIGH-ENTROPY ALLOY ; STACKING-FAULT ENERGY ; CRCONI ; THERMODYNAMICS ; DECOMPOSITION ; DEFORMATION ; NUCLEATION ; DUCTILITY ; MODELS |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| Funding Project | National Key Research and Devel-opment Program of the Ministry of Science and Technology of China[2019YFA0209902] ; Natural Science Foundation of China[11988102] ; Natural Science Foundation of China[11972350] |
| Funding Organization | National Key Research and Devel-opment Program of the Ministry of Science and Technology of China ; Natural Science Foundation of China |
| Classification | 二类/Q1 |
| Ranking | 1 |
| Contributor | Ma, En ; Wu, Xiao-Lei |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/96488 |
| Collection | 非线性力学国家重点实验室 |
| Affiliation | 1.Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China; 2.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China; 3.Xi An Jiao Tong Univ, Ctr Alloy Innovat & Design CAID, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China |
| Recommended Citation GB/T 7714 | Cao PY,Liu F,Yuan FP,et al. Multiple potential phase-separation paths in multi-principal element alloys[J]. MATERIALS TODAY NANO,2024,28:10.Rp_Au:Ma, En, Wu, Xiao-Lei |
| APA | 曹沛宇,刘峰,袁福平,Ma, En,&武晓雷.(2024).Multiple potential phase-separation paths in multi-principal element alloys.MATERIALS TODAY NANO,28,10. |
| MLA | 曹沛宇,et al."Multiple potential phase-separation paths in multi-principal element alloys".MATERIALS TODAY NANO 28(2024):10. |
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