| Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries | |
| Guo, Qiang; Mo WX(莫伟兴); Huang, Jianhang; Liu F(刘峰) | |
| Source Publication | NANO LETTERS
 |
| 2024-11 | |
| ISSN | 1530-6984 |
| Abstract | Highly stable aqueous Zn-ion batteries are of great importance for commercial applications. The challenging issues of interfacial side reactions and rampant dendrite growth cause short circuit and premature failure of aqueous Zn-ion batteries. Herein, a hydrated deep eutectic electrolyte is formulated to tackle such problems, which adopts 1,3-propanediol as a cosolvent. 1,3-Propanediol molecules can enter into the Zn2+ solvation structure to from a lean-water electrolyte and drastically diminish the activity of water molecules through reinforcing the hydrogen bond network. Meanwhile, PDO molecules exclude the neighboring water to modulate the electric double layer configuration, thus impeding water-mediated side reactions and inducing an inorganic-rich interphase. Consequently, this hydrated deep eutectic electrolyte ensures long-term stability of Zn-Zn, Zn-Cu, and Zn-I2 cells. The favorable influence exerted by PDO molecules provides the guidance for constructing high-performance aqueous Zn-ion batteries. |
| Keyword | deep eutectic electrolyte solvation structure inorganic-rich interphase Zn anode |
| DOI | 10.1021/acs.nanolett.4c03480 |
| Indexed By | SCI ; EI |
| Language | 英语 |
| WOS ID | WOS:001357805300001 |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS Subject | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| Funding Organization | Zhejiang Normal University ; Zhejiang Normal University |
| Classification | 一类 |
| Ranking | 1 |
| Contributor | Guo Q ; Liu F |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/97232 |
| Collection | 非线性力学国家重点实验室 |
| Affiliation | 1.【Guo, Qiang】 Zhejiang Normal Univ, Inst Sci & Applicat Mol Ferroelect, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China 2.【Mo, Weixing & Liu, Feng】 Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China 3.【Huang, Jianhang】 Zhejiang Normal Univ, Coll Chem & Mat Sci, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China |
| Recommended Citation GB/T 7714 | Guo, Qiang,Mo WX,Huang, Jianhang,et al. Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries[J]. NANO LETTERS,2024.Rp_Au:Guo Q, Liu F |
| APA | Guo, Qiang,莫伟兴,Huang, Jianhang,&刘峰.(2024).Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries.NANO LETTERS. |
| MLA | Guo, Qiang,et al."Reconfiguring the Coordination Structure in Deep Eutectic Electrolytes for Enabling Stable Operation of Zinc-Ion Batteries".NANO LETTERS (2024). |
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