Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride | |
Zhang,Siyi1; Li,Jingxuan1,2; Tian,Yu1; Fang,Shen1; Li,Chao1; Yu XL(余西龙)3,4; Jiang,Yue1,2; Yang,Lijun1,2 | |
Corresponding Author | Jiang, Yue([email protected]) |
Source Publication | COMBUSTION AND FLAME |
2025-02-01 | |
Volume | 272Pages:10 |
ISSN | 0010-2180 |
Abstract | Graphene fluoride (GF) with its two-dimensional structure and high fluorine content on the surface can be used to enhance the combustion characteristics of micron-sized Aluminum (mu Al) particles. However, the enhancing mechanisms of GF in Al combustion remain not fully understood. In this work, the effects of GF on combustion temperature, flame emission spectrum, ignition delay time, and condensed combustion products (CCPs) size of mu Al were studied using laser ignition and optical diagnostic experiments. The combustion characteristics of GFor polytetrafluoroethylene (PTFE)-modified mu Al composite particles were compared to elucidate the ignition and combustion mechanism of different fluorides. The results show that the thermal decomposition behavior and the energy distribution among excited Al atoms differ significantly between GF and PTFE. Compared with PTFE, GF and its decomposition products have stronger excitation ability for high energy Al atoms, which is conducive to increasing the combustion temperature of particle flame. In addition, the ignition delay time and CCPs size of Al/ GF are approximately 49 similar to 66 % and 10 % less than those of Al/PTFE, respectively. These results provide a fundamental understanding and data support for the application of functionalized graphene in metal fuels and solid propellants. |
Keyword | Aluminum particle Graphene fluoride Solid propellant Ignition delay Combustion mechanism |
DOI | 10.1016/j.combustflame.2024.113858 |
Indexed By | SCI ; EI |
Language | 英语 |
WOS ID | WOS:001361570600001 |
WOS Keyword | NANO-ALUMINUM ; IGNITION ; AGGLOMERATION ; REACTIVITY |
WOS Research Area | Thermodynamics ; Energy & Fuels ; Engineering |
WOS Subject | Thermodynamics ; Energy & Fuels ; Engineering, Multidisciplinary ; Engineering, Chemical ; Engineering, Mechanical |
Funding Project | National Natural Science Foundation of China[523B2063] |
Funding Organization | National Natural Science Foundation of China |
Classification | 一类/力学重要期刊 |
Ranking | 3+ |
Contributor | Jiang, Yue |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://dspace.imech.ac.cn/handle/311007/97502 |
Collection | 高温气体动力学国家重点实验室 |
Affiliation | 1.Beihang Univ, Sch Astronaut, Beijing 100191, Peoples R China; 2.Natl Key Lab Aerosp Liquid Prop, Xian 710100, Shaanxi, Peoples R China; 3.Chinese Acad Sci, State Key Lab High Temp Gas Dynam, Inst Mech, Beijing 100190, Peoples R China; 4.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Zhang,Siyi,Li,Jingxuan,Tian,Yu,et al. Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride[J]. COMBUSTION AND FLAME,2025,272:10.Rp_Au:Jiang, Yue |
APA | Zhang,Siyi.,Li,Jingxuan.,Tian,Yu.,Fang,Shen.,Li,Chao.,...&Yang,Lijun.(2025).Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride.COMBUSTION AND FLAME,272,10. |
MLA | Zhang,Siyi,et al."Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride".COMBUSTION AND FLAME 272(2025):10. |
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