IMECH-IR  > 高温气体动力学国家重点实验室
Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride
Zhang,Siyi1; Li,Jingxuan1,2; Tian,Yu1; Fang,Shen1; Li,Chao1; Yu XL(余西龙)3,4; Jiang,Yue1,2; Yang,Lijun1,2
Corresponding AuthorJiang, Yue([email protected])
Source PublicationCOMBUSTION AND FLAME
2025-02-01
Volume272Pages:10
ISSN0010-2180
AbstractGraphene fluoride (GF) with its two-dimensional structure and high fluorine content on the surface can be used to enhance the combustion characteristics of micron-sized Aluminum (mu Al) particles. However, the enhancing mechanisms of GF in Al combustion remain not fully understood. In this work, the effects of GF on combustion temperature, flame emission spectrum, ignition delay time, and condensed combustion products (CCPs) size of mu Al were studied using laser ignition and optical diagnostic experiments. The combustion characteristics of GFor polytetrafluoroethylene (PTFE)-modified mu Al composite particles were compared to elucidate the ignition and combustion mechanism of different fluorides. The results show that the thermal decomposition behavior and the energy distribution among excited Al atoms differ significantly between GF and PTFE. Compared with PTFE, GF and its decomposition products have stronger excitation ability for high energy Al atoms, which is conducive to increasing the combustion temperature of particle flame. In addition, the ignition delay time and CCPs size of Al/ GF are approximately 49 similar to 66 % and 10 % less than those of Al/PTFE, respectively. These results provide a fundamental understanding and data support for the application of functionalized graphene in metal fuels and solid propellants.
KeywordAluminum particle Graphene fluoride Solid propellant Ignition delay Combustion mechanism
DOI10.1016/j.combustflame.2024.113858
Indexed BySCI ; EI
Language英语
WOS IDWOS:001361570600001
WOS KeywordNANO-ALUMINUM ; IGNITION ; AGGLOMERATION ; REACTIVITY
WOS Research AreaThermodynamics ; Energy & Fuels ; Engineering
WOS SubjectThermodynamics ; Energy & Fuels ; Engineering, Multidisciplinary ; Engineering, Chemical ; Engineering, Mechanical
Funding ProjectNational Natural Science Foundation of China[523B2063]
Funding OrganizationNational Natural Science Foundation of China
Classification一类/力学重要期刊
Ranking3+
ContributorJiang, Yue
Citation statistics
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/97502
Collection高温气体动力学国家重点实验室
Affiliation1.Beihang Univ, Sch Astronaut, Beijing 100191, Peoples R China;
2.Natl Key Lab Aerosp Liquid Prop, Xian 710100, Shaanxi, Peoples R China;
3.Chinese Acad Sci, State Key Lab High Temp Gas Dynam, Inst Mech, Beijing 100190, Peoples R China;
4.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang,Siyi,Li,Jingxuan,Tian,Yu,et al. Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride[J]. COMBUSTION AND FLAME,2025,272:10.Rp_Au:Jiang, Yue
APA Zhang,Siyi.,Li,Jingxuan.,Tian,Yu.,Fang,Shen.,Li,Chao.,...&Yang,Lijun.(2025).Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride.COMBUSTION AND FLAME,272,10.
MLA Zhang,Siyi,et al."Probing the combustion characteristics of micron-sized aluminum particles enhanced with graphene fluoride".COMBUSTION AND FLAME 272(2025):10.
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